Product ID:FYROL CEF
MSDS Date:12/05/1996
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLDZK

AKZO NOBEL CHEMICALS INC.

5 LIVINGSTONE AVE
DOBBS FERRY, NY 10522
US

Emergency Phone: 914-693-6946/914-674-5000

Info Phone: 800-666-1200

Cage: 01GF0

AKZO NOBEL CHEMICALS INC.

DOBBS FERRY, NY 10522 US

Telephone: 800-666-1200

Cage: 01GF0

1). [SUBSTANCE IS A

CAS: 115-96-8

RTECS: KK2450000

OSHA PEL N/D

ACGIH TLV: N/D

ETHYLENE OXIDE.

CAS: 75-21-8

RTECS: KX2450000

Fraction By Weight: 0.001%

OSHA PEL 1.8 MG/M3

ACGIH TLV: 1.8 MG/M3;1 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

2-CHLOROETHANOL. (MFR PROVIDED CAS # 107-07-3).

Fraction By Weight: 0.010%

OSHA PEL C3.0 MG/M3

ACGIH TLV: C3.3 MG/M3

BIS(2-CHLOROETHYL) ETHER.

CAS: 111-44-4

RTECS: KN0875000

Fraction By Weight: .001-0.100%

OSHA PEL 30 MG/M3

ACGIH TLV: 29 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,2-DICHLOROETHANE

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.010%

OSHA PEL 200 MG/M3;C400 MG/M3

ACGIH TLV: 40 MG/M3;10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,4-DIOXANE

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: 0.010%

OSHA PEL 360 MG/M3

ACGIH TLV: 90 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONTAINS ETHYLENE OXIDE WHICH APPEARS
ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. SEEK
CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING SAFE
HANDLING AND EXPOSURE INFORMA TION . ACUTE: INHALATION: VAPOR, MIST
OR AEROSOL MAY CAUSE RESPIRATORY TRACT IRRITATION. SKIN: MAY CAUSE
MILD IRRITATION. EYE: NOT EXPECTED TO CAUSE IRRITATION. INGESTION:
PRODUCT IS MODERATEL Y TOXIC BY INGESTION BASED ON ANIMAL TESTS.
(CHRONIC) INHALATION: NOT KNOWN. SKIN: NOT KNOWN. TARGET ORGANS:
SKIN, RESPIRATORY TRACT, KIDNEYS, & BRAIN. MAY BE HARMFUL IF
SWALLOWED. MAY CAUSE MILD SKIN IRRITATION, RESPIRATORY
(OVEREXPOSURE)
Explanation of Carcinogenicity:ETHYLENE OXIDE; 1,2-DICHLOROETHANE; 1,4
DIOXANE ARE LISTED AS CARCINOGENS BY NTP AND IARC. HOWEVER, THE
PERCENTAGES OF THESE INGREDIENTS IN THE PRODUCT ARE LESS THAN 0.1%
.
Effects of Overexposure:ACUTE/CHRONIC (CONT'D): TRACT INFECTION, KIDNEY
& BRAIN EFFECTS-BASED ON ANIMAL DATA. NOTE TO PHYSICIAN: PRODUCT
IS ORGANOPHOSPHORUS MIXTURE. THIS CLASS OF COMPOUNDS CAN TYPICALLY
CAUSE CHOLINESTERAS E INHIBITION. HUMAN SYMPTOMS OF INHIBITION MAY
INCLUDE SALIVATION, SWEAT, HEADACHE, NAUSEA, MUSCLE TWITCH,
TREMORS, INCOORDINATION, BLURRED VISION, TEARS, ABDOMINAL CRAMPS,
DIARRHEA, &/OR CHEST DISCOM FORT. HUMAN EXPERIENCE & ANIMAL TESTS
HAVE NOT SHOWN PRODUCT TO BE CHOLINESTERASE INHIBITOR. FOR
ADDITIONAL DETAILS AND TOXICOLOGICAL DATA CONTACT NEHC .
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
NEUROMUSCULAR DISORDERS MAY BE AT AN INCREASED RISK FROM EXPOSURE
TO THIS MATERIAL.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. GET MED ATTN. SKIN CONT: REMOVE CONTAM
CLTHG & EQUIP. THOROUGHLY WASH ALL AFFECTED AREAS W/SOAP & PLENTY
OF WATE R. GET MED ATTN IF IRRIT PERSISTS. WASH CONTAM CLTHG BEFORE
REUSE. THOROUGHLY CLEAN OR DESTROY CONTAM SHOES. EYE CONT: IMMED
FLUSH EYES W/PLENTY OF RUNNING WATER. IF VICTIM IS WEARING CONTACT
LENSES, REMOVE THEM. HOLD EYELIDS APART DURING FLUSHING TO ENSURE
RINSING OF ENTIRE SURFACE OF EYE & LIDS W/WATER. GET MED ATTN IF
IRRIT PERSISTS. INGEST: GET MED ATTN BY CALLING MD OR POIS CTL CTR
IMMED. D O NOT INDUCE VOMIT (OTHER INFO)

Flash Point Method:COC
Flash Point:=251.7C, 485.F
Autoignition Temp:=537.8C, 1000.F
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:WATER FOG OR SPRAY, DRY CHEMICAL, FOAM OR CARBON
DIOXIDE. EXTING MEDIA (CONT): OR FIRE HAZ. DIKE FIRE CONTROL WATER
FOR LATER DISPOSAL. DO NOT ALLOW CONTAM WATER TO ENTER WATERWAYS.
Fire Fighting Procedures:PREVENT HUMAN EXPOSURE TO FIRE,SMOKE, FUMES,
PRODUCTS OF COMBUSTION. EVAC NON-ESSNTL PERS FROM FIRE AREA. USE
NIOSH APPROVED SCBA/IMPERVIOUS PROTECTIVE CLOTHING. IF POSS, MOVE
CONTRS FROM FIRE AREAS. IF NOT LEAKING, KEEP FIRE EXPOS CONTRS
COOL W/WATER FOG, SPRAY TO PVNT RUPTURE DUE TO HIGH HEAT(UNUSUAL
FIRE/EXPLO HAZ)
Unusual Fire/Explosion Hazard:NOT DEFINED AS FLAMMABLE/COMBUSTBILE.
SELF-EXTING ONCE SOURCE OF IGNIT IS REMOVED. NOT SENSITIVE TO
STATIC DISCHARGE/PHYSICAL IMPACT. MAY DECOMP UNDER FIRE CNDTNS. NO
OTHER FIRE/EXPLOSION HAZ OF PROD ARE KNOWN. FIREFIGHT (CONT'D):
HIGPRESS WATER MAY SPREAD PROD FROM BROKEN CONTRS INCREASING FIRE
CONTAM (EXTING MEDIA)

Spill Release Procedures:ISOLATE SPILL & RESTRICT NONESSENTIAL
PERSONNEL. PERS INVOLVED IN SPILL CLEANUP FOLLOW APPROP INDUSTRIAL
HYGIENE PRACTICES. STOP SOURCE OF SPILL. DIKE AREA TO PREVENT SPILL
FROM SPREADING. SOAK UP LI QUID W/SUITABLE ABSORBENT SUCH AS CLAY,
SAWDUST, OR KITTY LITTER. SWEEP UP ABSORBENT MATL & PLACE IN CHEM
WASTE CONTAINER FOR DISPOSAL. CAUTION! SPILL AREA MAY BE (OTHER
INFO)

Handling and Storage Precautions:WEAR PROTECTIVE CLOTHING, INCLUDING
CHEM GOGGLES & RUBBER GLOVES WHEN HANDLING PRODUCT TO AVOID
EYE/SKIN CONTACT. HANDLE IN WELL-VENTILATED AREA. AVOID INHALATION
OF VAPOR/MIST. WASH THOROUGHLY AFTER HANDLING. CONTAINER SHOULD BE
LOCATED IN AREA WHERE THEY CAN BE ROTATED (FIRST IN, FIRST OUT)
(SARA)
Other Precautions:N/P. DISPOSAL (CONTD): GENERATORS OF WASTES ARE
REQUIRED TO EVALUATE MATERIALS FOR COMPLIANCE W/RCRA & LOCAL
DISPOSAL PROCEDURES & REGS. CONTAINERS SHOULD BE DRAINED OF
RESIDUAL PRODUCT BEFORE DISPOS AL. EMPTY CONTAINERS SHOULD BE
DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE FED, STATE, & LOCAL
RE GULATIONS.

Respiratory Protection:USE NIOSH APPRVD ORGANIC VAPOR/ACID GAS RESP
W/DUST, MIST, & FUME FILTERS TO REDUCE POTENTIAL FOR INHAL EXPOS IF
USE CONDITIONS GENERATE VAPOR, MIST, OR AEROSOL & ADEQUATE VENT IS
NOT AVAIL. WHERE EXP OS POTENTIAL NECESSITATES HIGHER LEVEL OF
PROT, USE NIOSH APPRVD, POS-PRESS, PRESS DEMAND, AIR-SUPP RESP,
CHANGE CARTRIDGES/CANNISTERS FREQ (SUPP SFTY)
Ventilation:AT ELEVATED PROCESSING TEMPS, OR IF USE CONDITIONS GENERATE
AIRBORNE VAPOR, AEROSOL OR MIST, MATL SHOULD BE USE IN
WELL-VENTILATED AREA.
Protective Gloves:NITRILE RUBBER GLOVES RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES & FULL FACESHIELD
.
Other Protective Equipment:SUITABLE PROTECTIVE CLOTHING & FOOTWEAR.
SAFETY SHOWERS, WITH QUICK OPENING VALVES WHICH STAY OPEN, & EYE
WASH FOUNTAINS, OR OTHER MEANS OF WASHING EYES WITH GENTLE FLOW OF
COOL TO TEPID (SUPP SAFETY)
Work Hygienic Practices:WASH COMTAMINATED CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN OR DESTROY CONTAMINATED SHOES. CHEMICAL FORMULA:
C6 H12 C13 O4 P. CHEM FAMILY: ALKYL PHOSPHATE. CAS # 115-96-8.
Supplemental Safety and Health
RESP)IRATORY (CONT'D): (FOLLOWING EACH USE/END OF WORKSHIFT) TO ASSURE
BREAKTHRU EXPOS DOES NOT OCCUR. OTHER PROT EQUIP (CONT'D): WATER.
WATER SHOULD BE SUPPLIED THRU INSULATED/HEAT-TRACED LINES TO PR
EVENT FREEZE-UPS. SYNONYMS: ETHANOL, 2-CHLORO-, PHOSPHATE;
PHOSPHORIC ACID, TRI(2-CHOLROETHYL) ESTER.

Boiling Pt:=145.C, 293.F
B.P. Text:@ 0.5 MM HG.
Melt/Freeze Pt:M.P/F.P Text:N/D
Vapor Pres:LT 10 @ 77F (25C)
Vapor Density:N/D
Spec Gravity:1.42 @ 77F (25C)
pH:N/D
Viscosity:@ 77F (25C)=38 CPS.
Evaporation Rate & Reference:N/D
Solubility in Water:0.7 G/100 G @ 68F (20C).
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH A SLIGHT ODOR.
Percent Volatiles by Volume:N/D

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZERS, STRONG ACIDS & STRONG ALKALIS.
HYDROLYZES SLOWLY & AMBIENT TEMPS IN NEUTRAL OR ALKALINE AQUEOUS
SOLUTIONS. STABILITY COND TO AVOID (CONT'D): CONDITIONS IN ABSENCE
OF MOISTURE. AVOID PROLONG
Stability Condition to Avoid:SLIGHT INCREASE IN ACIDITY IS NORM DURING
STOR. PROD IS STABLE @ AMBIENT TEMP & ATMOSPHERIC PRESS. PROD IS
NOT SELF-REACTIVE & HAS VERY LONG SHELF LIFE UNDER SEALED (MATL TO
AVOID).
Hazardous Decomposition Products:UNDER FIRE CONDITIONS: CARBON
MONOXIDE, CARBON DIOXIDE, PHOSPHORUS OXIDES, AND HYDROGEN CHLORIDE
GAS. UNDER WET ALKALINE/NEUTRAL CONDITIONS: PROD HYDROLYZES SLOWLY
AND NON-VIOLENTLY.
Conditions to Avoid Polymerization:MATERIAL TO AVOID (CONT'D): STORAGE
AT ELEVATED TEMPS UNDER WET CONDITIONS. PREVENT MOISTURE FROM
CONDENSING IN CONTAINER.

Waste Disposal Methods:MATERIAL THAT CANNOT BE USED OR CHEMICALLY
REPROCESSED SHOULD BE DISPOSED OF IN ACCORDANCE W/ALL APPLICABLE
FED, STATE, & LOCAL REGS. PRODUCT CONTAINERS DESIGNED FOR SINGLE
USE SHOULD BE THOROUGHLY E MPTIED BEFORE DISPOSAL. PRODUCT, IF
UNUSED, DOES NOT MEET EPA'S RCRA CRITERIA AS EITHER LISTED OR CH
ARACTERISTIC HAZARDOUS WASTE (OTHER PRECAUTIONS)

Toxicological Information:ACUTE: INHAL: 4-HR. LC50 IN BOTH MALE &
FEMALE RATS IS > 5000 MG/M3 (> 94% RESPIRABLE). NO MORTALITIES WERE
RPTD AT THIS EXPOS LEVEL. DERMAL: PRACTICALLY NON-TOXIC; DERMAL:
LD50 IS > 5000 MG/KG IN RAB BITS. PROD IS A MILD IRRIT TO RABBIT
SKIN FOLLOWING A 24 HR. EXPOS. EYE: NON-IRRIT TO RABBIT EYES.
INGEST: MOD TOX; COMBINED ACUTE ORAL LD50 FOR MALE & FEMALE RATS IS
550 MG/KG. NECROPSY FINDINGS IN BOTH MALE & FEMALE RATS INCL
APPARENT HEMORRHAGES IN STOMACH & INTESTINES. CHRONIC: INGEST: RATS
& MICE WERE GIVEN ORAL DOSES RANGING FROM 22-350 & 44-700
MG/KG/DAY, RESPECTIVELY, OF TEST MATL 5 DAYS/ WEEK FOR 16-18 WKS.
(TRANSPORT).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICOLOGICAL: 24-HOUR EC50 IN DAPHINA IS 235 MG/L.
96-HOUR LC50 IN RAINBOW TROUT IS 249/L. 96-HOUR LC50 IN KILLFISH IS
210 MG/L. 96-HOUR LC50 IN GOLDFISH IS 90 MG/L. TRI(2-CHLOROETHYL)
PHOSPHATE WAS NOT DETECTED IN BODIES OF KILLFISH OR GOLDFISH
LIVING FOR 100 HRS IN WATER W/CONC RANGING FROM 0.25 - 4 MG/L.
TRI(2-CHLOROETHYL) PHOSPHATE MAY BE STABLE TO CHEM DEGRADATION IN
WATER HAVING ACIDIC PH; HOWEVER, DECOMP MAY OCCUR IN NEUT OR
ALKALINE WATERS. MATL IS EXPECTED TO BE MOBILE IN SOIL &
SUSCEPTIBLE TO SIGNIFICANT LEACHING. IT IS EXPECTED TO RESIST
BIODEGRADATION. OTHER ECOLOGICAL INFO ON PRODUCT IS NOT KNOWN.

Transport Information:SHIPPING DESCRIPT: PROD IS NOT REGULATED AS HAZ
MATL FOR EITHER DOMESTIC OR INTERNATIONAL TRANSPORT BY ANY MODE.
REQ'D LABELS: NOT REGULATED FOR SHIPPING; NO TRANSPORT LABELS
REQ'D. ENVIRONMENTAL HAZ SUBSTANCE: DOES NOT CONTAIN AN
ENVIRONMENTALLY HAZ SUBSTANCE PER 49 CFR 172.101, APPENDIX A. TOX
(CONT'D): MORTALITY WAS NOTED IN RATS IN HIGH DOSE GROUP ONLY;
THERE WAS NO MORTALITY NOTED IN MICE. P ROD USE: FLAME
RETARDANT/PLASTICIZER. MATL IS NONCORR TO GLASS/METALS. HOWEVER,
BECAUSE MATL HAS PLASTICIZING PROPS, IT MAY SOFTEN/DETERIORATE
CERTAIN PLASTICS & ELASTOMERS (PARTICULARLY VINYL-BASED R ESINS,
NEOPRENE, & NATURAL RUBBERS).

SARA Title III Information:SUBJECT TO SARA TITLE III, SECTIONS 302 &
313:ETHYLENE OXIDE, 2-CHLOROETHANOL, BIS(2-CHLOROETHYL) ETHER, &
1,2-DICHLOROETHANE. SUBJ TO SARA TITLE III, SEC 313: 1,4-DIOXANE.
HNDLG/STOR (CONT'D): & VISUALLY INSPECTED FOR DENTS, BULGING ON
WEEKLY BASIS. VENT BULGED DRUMS IN OPEN AREA BY REMOVING TWO-INCH
BUNG VERY SLOWLY. BUNG SHOULD NOT BE REMOVED COMPLETELY UNTIL THERE
IS NO SOUND OF PRESS BEIN G RELEASED. BUNG CAN THEN BE REMOVED, BUT
DONE SLOWLY & W/CARE. EMPTIED CONTR MAY RETAIN PROD RESIDUES. FOL
ALL WARNING,PRECAUTS EVEN AFTER CONTR IS EMPTIED. STOR: STORE AWAY
FROM FOODSTUFFS & ANIMAL FEED, (STATE REG)
Federal Regulatory Information:LISTED ON TSCA: ETHANOL,
2-CHLORO-,PHOSPHATE (3:1), ETHYLENE OXIDE, 2-CHLOROETHANOL,
BIS(2-CHLOROETHYL) ETHER, 1,2-DICHLOROETHANE, 1,4-DIOXANE. SUBJ TO
CAA SECT. 112: ETHYLENE OXIDE, BIS(2-CHLOROETH YL) ETHER,
1,2-DICHLOROETHANE, & 1,4-DIOXANE. SUBJ TO CERCLA HAZ SUBSTANCES:
ETHYLENE OXIDE, 2-CHLOROETHANOL,BIS(2-CHLOROETHYL)
ETHER,1,2-DICHLOROETHANE, & 1,4-DIOXANE. SUBJ TO IARC
CARCINOGENS-GRP S, 1,2A,2B: ETHYLENE OXIDE, 1,2-DICHLOROETHANE, &
1,4-DIOXANE. SUBJ TO CANADIAN DOMESTIC SUBSTANCE LIST: ETHANOL,
2-CHLORO-,PHOSPHATE (3:1), ETHYLENE OXIDE, 2-CHLOROETHANOL,
BIS(2-CHLOROETHYL) ETHER, 1,2-DICHLOROETHANE, & 1,4-DIOXANE.
State Regulatory Information:SUBJ TO MA SUBSTANCE LIST, NJ R-T-K HAZARD
SUB., & PA HAZ SUBSTANCE LIST: ETHYLENE OXIDE, 2-CHLOROETHANOL,
BIS(2-CHLOROETHYL) ETHER, 1,2-DICHLOROETHANE, & 1,4-DIOXANE.
SUBJECT TO CA PROP 65: ETHANOL, 2-CHLORO-,PHOSPHATE (3:1),
ETHYLENE OXIDE, BIS(2-CHLOROETHYL) ETHER, 1,2-DICHLOROETHANE, &
1,4-DIOXANE. PRODUCT CONTAIN CHEMICALS KNOWN TO STATE OF CA TO
CAUSE CANCER/REPRODUCTIVE TOXICITY. SARA (CONT 'D): STORE IN
COOL,DRY, WELL VENT AREA AWAY FROM FLAMM/OXIDIZING MATLS & SOURCES
OF HEAT/FLAME. ST ORE BELOW 122F (50C) TO MIN PROD DEGRADATION.
USE CAUTION TO PREVENT DAMAGE TO OR LEAKAGE FROM CONTAINER. MAXIMUM
STORAGE TEMP: 122 F; 50C.